ID 2.3.1.277 DE 2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate synthase. CA a medium-chain 3-oxoacyl-[ACP] + dihydroxyacetone phosphate = a 2-oxo-3- CA (phosphooxy)propyl medium-chain 3-oxoalkanoate + holo-[ACP]. CC -!- The enzyme catalyzes the first committed step in the biosynthesis of CC gamma-butyrolactone autoregulators that control secondary metabolism CC and morphological development in Streptomyces bacteria. DR B1VN93, AFSA_STRGG ; P18394, AFSA_STRGR ; O24738, BARX_STRVG ; DR Q7AKF0, SCBA_STRCO ; //