ID 2.5.1.132 DE 3-deoxy-D-glycero-D-galacto-nononate 9-phosphate synthase. AN 2-keto-3-deoxy-D-glycero-D-galacto-9-phosphonononic acid synthase. AN KDN 9-P synthase. CA D-mannose 6-phosphate + H2O + phosphoenolpyruvate = 3-deoxy-D-glycero- CA beta-D-galacto-non-2-ulopyranosonate 9-phosphate + phosphate. CC -!- The enzyme participates in the biosynthesis of the sialic acid CC 3-deoxy-D-glycero-D-galacto-nononate (KDN). CC -!- The human sialic acid synthase (EC 2.5.1.57) is also able to catalyze CC the reaction. CC -!- KDN is abundant in extracellular glycoconjugates of lower vertebrates CC such as fish and amphibians, but is also found in the capsular CC polysaccharides of bacteria that belong to the Bacteroides genus. //