ID 2.7.1.227 DE inositol phosphorylceramide synthase. CA an N-(2R-hydroxy-very-long-chain fatty acyl)-(R)-4-hydroxysphingoid base CA + a 1,2-diacyl-sn-glycero-3-phospho-(1D-myo-inositol) = a 1D-myo- CA inositol-1-phospho-N-[(R)-2-hydroxy-very-long-chain fatty acyl]-(R)-4- CA hydroxysphingoid base + a 1,2-diacyl-sn-glycerol. CC -!- The enzyme, characterized from yeast, attaches a phosphoinositol CC headgroup to alpha-hydroxyphytoceramides, generating a very-long- CC chain inositol phospho-alpha hydroxyphytoceramide (IPC), the simplest CC of the three complex sphingolipids produced by yeast. DR P36107, AUR1_YEAST ; Q84WB7, GINT1_ARATH; Q9SH93, IPCS2_ARATH; //