ID 2.7.9.5 DE phosphoglucan, water dikinase. CA [(1->4)-6-phospho-alpha-D-glucosyl](n) + n ATP + n H2O = [(1->4)-3,6- CA bisphospho-alpha-D-glucosyl](n) + n AMP + 2n H(+) + n phosphate. CC -!- The enzyme phosphorylates granular starch that has previously been CC phosphorylated by EC 2.7.9.4; there is no activity with CC unphosphorylated glucans. CC -!- It transfers the beta-phosphate of ATP to the phosphoglucan, whereas CC the gamma-phosphate is transferred to water. CC -!- In contrast to EC 2.7.9.4, which phosphorylates the glucose groups in CC glucans predominantly on O-6, this enzyme phosphorylates glucose CC groups in phosphorylated starch predominantly on O-3. CC -!- The protein phosphorylates itself with the beta-phosphate of ATP, CC which is then transferred to the glucan. DR Q6ZY51, PWD_ARATH ; Q2QTC2, PWD_ORYSJ ; //