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ENZYME

ENZYME entry: EC 3.1.1.78

PURL: https://purl.expasy.org/enzyme/EC/3.1.1.78
Accepted Name
polyneuridine-aldehyde esterase
Alternative Name(s)
PNAE
polyneuridine aldehyde esterase
Reaction catalysed
polyneuridine aldehyde + H2O = 16-epivellosimine + methanol + CO2
Comment(s)
  • Following hydrolysis of this indole alkaloid ester, the carboxylic acid decarboxylates spontaneously giving the sarpagan skeleton.
  • Also acts on akuammidine aldehyde (the 16-epimer of polyneuridine aldehyde).
Cross-references
BRENDA3.1.1.78
EC2PDB3.1.1.78
ExplorEnz3.1.1.78
KEGG Ligand Database for Enzyme Nomenclature3.1.1.78
IUBMB Enzyme Nomenclature3.1.1.78
MEDLINEFind literature relating to 3.1.1.78
MetaCyc3.1.1.78
Rhea expert-curated reactions3.1.1.78
UniProtKB/Swiss-Prot
Q9SE93, PNAE_RAUSE

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