ENZYME entry: EC 3.1.1.78
Accepted Name |
Polyneuridine-aldehyde esterase.
|
Alternative Name(s) |
PNAE. |
Polyneuridine aldehyde esterase. |
Reaction catalysed |
Polyneuridine aldehyde + H(2)O <=> 16-epivellosimine + CO(2) + methanol |
Comment(s) |
- Following hydrolysis of this indole alkaloid ester, the carboxylic
acid decarboxylates spontaneously giving the sarpagan skeleton.
- Also acts on akuammidine aldehyde (the 16-epimer of polyneuridine
aldehyde).
|
Cross-references |
BRENDA | 3.1.1.78 |
EC2PDB | 3.1.1.78 |
ExplorEnz | 3.1.1.78 |
PRIAM enzyme-specific profiles | 3.1.1.78 |
KEGG Ligand Database for Enzyme Nomenclature | 3.1.1.78 |
IUBMB Enzyme Nomenclature | 3.1.1.78 |
IntEnz | 3.1.1.78 |
MEDLINE | Find literature relating to 3.1.1.78 |
MetaCyc | 3.1.1.78 |
UniProtKB/Swiss-Prot |
|
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