ID   3.1.3.77
DE   acireductone synthase.
AN   E-1 enolase-phosphatase.
CA   5-methylsulfanyl-2,3-dioxopentyl phosphate + H2O = 1,2-dihydroxy-5-
CA   (methylsulfanyl)pent-1-en-3-one + phosphate.
CC   -!- This bifunctional enzyme first enolizes the substrate to form the
CC       intermediate 2-hydroxy-5-(methylsulfanyl)-3-oxopent-1-enyl phosphate,
CC       which is then dephosphorylated to form the acireductone 1,2-
CC       dihydroxy-5-(methylsulfanyl)pent-1-en-3-one.
CC   -!- The acireductone represents a branch point in the methione salvage
CC       pathway as it is used in the formation of formate, CO and
CC       3-(methylsulfanyl)propanoate by EC 1.13.11.53 and of formate and
CC       4-(methylsulfanyl)-2-oxobutanoate either by a spontaneous reaction
CC       under aerobic conditions or by EC 1.13.11.54.
DR   C4WUT0, ENOPH_ACYPI;  Q17Q32, ENOPH_AEDAE;  Q7Q9C0, ENOPH_ANOGA;
DR   A6SRT0, ENOPH_BOTFB;  Q0VD27, ENOPH_BOVIN;  C3XR70, ENOPH_BRAFL;
DR   A8Y461, ENOPH_CAEBR;  Q21012, ENOPH_CAEEL;  Q5AM80, ENOPH_CANAL;
DR   C4YJE1, ENOPH_CANAW;  B9WAM8, ENOPH_CANDC;  Q6FLR5, ENOPH_CANGA;
DR   C5M5Z6, ENOPH_CANTT;  Q2H683, ENOPH_CHAGB;  C4Y3W1, ENOPH_CLAL4;
DR   B0WQG0, ENOPH_CULQU;  Q6GMI7, ENOPH_DANRE;  Q6BXC7, ENOPH_DEBHA;
DR   Q55FM6, ENOPH_DICDI;  B3M173, ENOPH_DROAN;  B3P2A7, ENOPH_DROER;
DR   B4JSP3, ENOPH_DROGR;  Q9VN95, ENOPH_DROME;  B4KCL9, ENOPH_DROMO;
DR   B4GFE6, ENOPH_DROPE;  Q296B0, ENOPH_DROPS;  B4I3X6, ENOPH_DROSE;
DR   B4QW91, ENOPH_DROSI;  B4M4X4, ENOPH_DROVI;  B4NI64, ENOPH_DROWI;
DR   B4PV71, ENOPH_DROYA;  Q753F5, ENOPH_EREGS;  C7Z9X4, ENOPH_FUSV7;
DR   Q9UHY7, ENOPH_HUMAN;  Q6CM87, ENOPH_KLULA;  C4R1T9, ENOPH_KOMPG;
DR   C5DDS4, ENOPH_LACTC;  A5DUA7, ENOPH_LODEL;  A9V2Y9, ENOPH_MONBE;
DR   Q8BGB7, ENOPH_MOUSE;  D2UYP1, ENOPH_NAEGR;  Q7SBS7, ENOPH_NEUCR;
DR   A5DIR2, ENOPH_PICGU;  A3LRM2, ENOPH_PICST;  B2AWZ9, ENOPH_PODAN;
DR   A4RM80, ENOPH_PYRO7;  Q5PPH0, ENOPH_RAT  ;  B5X2D1, ENOPH_SALSA;
DR   B6JXU1, ENOPH_SCHJY;  Q9P6Q2, ENOPH_SCHPO;  A7E3Z4, ENOPH_SCLS1;
DR   D1ZPB8, ENOPH_SORMK;  A7TN25, ENOPH_VANPO;  C9SUS0, ENOPH_VERA1;
DR   Q569R5, ENOPH_XENLA;  Q28C69, ENOPH_XENTR;  Q6C8V1, ENOPH_YARLI;
DR   B3LRX9, ENOPH_YEAS1;  C7GKE1, ENOPH_YEAS2;  B5VH97, ENOPH_YEAS6;
DR   A6ZQR2, ENOPH_YEAS7;  P32626, ENOPH_YEAST;  C5DXI0, ENOPH_ZYGRC;
DR   E0CSI1, MTBC1_VITVI;  E0CTF3, MTBC2_VITVI;  Q9FN41, MTBC_ARATH ;
DR   B4G0F3, MTBC_MAIZE ;  B8BKI7, MTBC_ORYSI ;  Q2R483, MTBC_ORYSJ ;
DR   A9RBS1, MTBC_PHYPA ;  B9N1F9, MTBC_POPTR ;  B9SQI7, MTBC_RICCO ;
DR   C6JS30, MTBC_SORBI ;  A5FUG6, MTNC_ACICJ ;  Q0VPK3, MTNC_ALCBS ;
DR   O67786, MTNC_AQUAE ;  C1DHH2, MTNC_AZOVD ;  A5EES8, MTNC_BRASB ;
DR   A8ANI1, MTNC_CITK8 ;  A7MK11, MTNC_CROS8 ;  Q3ZUZ9, MTNC_CROSK ;
DR   A4W7Z3, MTNC_ENT38 ;  B2VIR2, MTNC_ERWT9 ;  Q0RQV6, MTNC_FRAAA ;
DR   A9H8G7, MTNC_GLUDA ;  Q5FRJ1, MTNC_GLUOX ;  Q0BPT7, MTNC_GRABC ;
DR   Q2SKZ0, MTNC_HAHCH ;  B4U605, MTNC_HYDS0 ;  P0C8L5, MTNC_KLEAE ;
DR   Q48389, MTNC_KLEOX ;  B5XZU3, MTNC_KLEP3 ;  A6T673, MTNC_KLEP7 ;
DR   B0SFG5, MTNC_LEPBA ;  Q04QY0, MTNC_LEPBJ ;  Q04Z87, MTNC_LEPBL ;
DR   B0SP16, MTNC_LEPBP ;  Q72NW0, MTNC_LEPIC ;  Q8F7L5, MTNC_LEPIN ;
DR   A1TZ36, MTNC_MARN8 ;  Q60AP9, MTNC_METCA ;  Q5YQZ4, MTNC_NOCFA ;
DR   A7HU88, MTNC_PARL1 ;  Q7U4U9, MTNC_PARMW ;  Q6D1G2, MTNC_PECAS ;
DR   C6DCZ3, MTNC_PECCP ;  C0QPL9, MTNC_PERMH ;  B1XPT1, MTNC_PICP2 ;
DR   A2CBQ3, MTNC_PROM3 ;  Q7V8Y7, MTNC_PROMM ;  Q48KM6, MTNC_PSE14 ;
DR   A6V7A6, MTNC_PSEA7 ;  B7UV36, MTNC_PSEA8 ;  Q02KH5, MTNC_PSEAB ;
DR   Q9I340, MTNC_PSEAE ;  Q3KFI7, MTNC_PSEPF ;  Q884P1, MTNC_PSESM ;
DR   Q4ZVB8, MTNC_PSEU2 ;  A4FFQ6, MTNC_SACEN ;  A8GAA9, MTNC_SERP5 ;
DR   A1S1N0, MTNC_SHEAM ;  B8E3J4, MTNC_SHEB2 ;  A3DAG6, MTNC_SHEB5 ;
DR   A6WHG9, MTNC_SHEB8 ;  A9KV69, MTNC_SHEB9 ;  Q12T52, MTNC_SHEDO ;
DR   Q07W23, MTNC_SHEFN ;  B0TM50, MTNC_SHEHH ;  A3QJI9, MTNC_SHELP ;
DR   Q8EKK8, MTNC_SHEON ;  A8HAA3, MTNC_SHEPA ;  A4Y1H2, MTNC_SHEPC ;
DR   B8CGX4, MTNC_SHEPW ;  A0KRB5, MTNC_SHESA ;  A8G1T3, MTNC_SHESH ;
DR   Q0HP46, MTNC_SHESM ;  Q0I0L4, MTNC_SHESR ;  A1RQ67, MTNC_SHESW ;
DR   B1KPZ1, MTNC_SHEWM ;  A9FCY5, MTNC_SORC5 ;  Q828K9, MTNC_STRAW ;
DR   B4STR0, MTNC_STRM5 ;  B2FPP2, MTNC_STRMK ;  B2V7G7, MTNC_SULSY ;
DR   Q31LP5, MTNC_SYNE7 ;  Q5N078, MTNC_SYNP6 ;  A5GJ48, MTNC_SYNPW ;
DR   A5GR42, MTNC_SYNR3 ;  Q3AWF3, MTNC_SYNS9 ;  Q3AMB9, MTNC_SYNSC ;
DR   B8GMB3, MTNC_THISH ;  Q8PLG2, MTNC_XANAC ;  Q3BUE8, MTNC_XANC5 ;
DR   Q4UU49, MTNC_XANC8 ;  B0RSM3, MTNC_XANCB ;  Q8P9N5, MTNC_XANCP ;
DR   Q2P3W6, MTNC_XANOM ;  B2SM84, MTNC_XANOP ;  Q5H0Y0, MTNC_XANOR ;
DR   A7IJF6, MTNC_XANP2 ;  B2I5X4, MTNC_XYLF2 ;  Q9PBD3, MTNC_XYLFA ;
DR   B0U3A6, MTNC_XYLFM ;  Q87C36, MTNC_XYLFT ;  A1JP11, MTNC_YERE8 ;
DR   A7FLL3, MTNC_YERP3 ;  B2K631, MTNC_YERPB ;  A9R2Z7, MTNC_YERPG ;
DR   A4TPN1, MTNC_YERPP ;  Q66E18, MTNC_YERPS ;  B1JIK5, MTNC_YERPY ;
//