ID 3.2.1.189 DE dioscin glycosidase (diosgenin-forming). AN dioscin glycosidase (aglycone-forming). CA dioscin + 3 H2O = D-glucose + diosgenin + 2 L-rhamnopyranose. CC -!- The enzyme is involved in degradation of the steroid saponin dioscin CC by some fungi of the Absidia genus. CC -!- The enzyme can also hydrolyze 3-O-[alpha-L-Ara-(1->4)-[alpha-L-Rha- CC (1->2)]-beta-D-Glc]diosgenin into diosgenin and free sugars as the CC final products. CC -!- (cf. EC 3.2.1.190). //