ID   4.2.1.121
DE   colneleate synthase.
AN   9-DES.
AN   9-divinyl ether synthase.
AN   CYP74D.
AN   CYP74D1.
CA   (9S)-hydroperoxy-(10E,12Z)-octadecadienoate = colneleate + H2O.
CC   -!- It catalyzes the selective removal of pro-R hydrogen at C-8 in the
CC       biosynthesis of colneleic acid.
CC   -!- It forms also (8E)-9-[(1E,3Z,6Z)-nona-1,3,6-trien-1-yloxy]non-8-enoic
CC       acid (i.e. colnelenate) from (9Z,10E,12Z,15Z)-9-hydroperoxy-10,12,15-
CC       octadecatrienoate.
CC   -!- The corresponding 13-hydroperoxides are poor substrates.
CC   -!- The divinyl ethers colneleate and colnelenate have antimicrobial
CC       activity.
DR   Q0PHS9, DES_CAPAN  ;  Q9FPM6, DES_SOLLC  ;  Q9AVQ1, DES_SOLTU  ;
DR   Q8W2N5, DES_TOBAC  ;
//