ID   4.2.1.92
DE   hydroperoxide dehydratase.
AN   allene oxide synthase.
AN   AOS.
AN   hydroperoxide isomerase.
CA   (13S)-hydroperoxy-(9Z,11E,15Z)-octadecatrienoate = (9Z,13S,15Z)-12,13-
CA   epoxyoctadeca-9,11,15-trienoate + H2O.
CC   -!- Acts on a number of unsaturated fatty-acid hydroperoxides, forming
CC       the corresponding allene oxides.
CC   -!- The product of the above reaction is unstable and is acted upon by
CC       EC 5.3.99.6 to form the cyclopentenone derivative (15Z)-12-oxophyto-
CC       10,15-dienoate (OPDA), which is the first cyclic and biologically
CC       active metabolite in the jasmonate biosynthesis pathway.
DR   K4BV52, AOS1_SOLLC ;  Q9LLB0, AOS2_SOLLC ;  Q8GZP5, AOS3_SOLLC ;
DR   Q7Y0C8, C74A1_ORYSJ;  Q7XYS3, C74A2_ORYSJ;  Q40778, C74A2_PARAR;
DR   Q6Z6L1, C74A3_ORYSJ;  Q6Z6K9, C74A4_ORYSJ;  Q96242, CP74A_ARATH;
DR   P48417, CP74_LINUS ;
//