ID   4.2.3.221
DE   macrophomene synthase.
CA   all-trans-hexaprenyl diphosphate = macrophomene + diphosphate.
CC   -!- Isolated from Macrophomina phaseolina, a pathogenic fungus that
CC       causes damping off, seedling blight, collar rot, stem rot, charcoal
CC       rot, basal stem rot, and root rot on many plant species.
CC   -!- The 22-membered ring in macrophomene represents the largest
CC       macrocycle discovered in terpenes so far.
DR   K2SUY0, MPMS_MACPH ;
//