ID   4.3.1.30
DE   dTDP-4-amino-4,6-dideoxy-D-glucose ammonia-lyase.
CA   AH2 + dTDP-4-amino-4,6-dideoxy-alpha-D-glucose + S-adenosyl-L-methionine
CA   = 5'-deoxyadenosine + A + dTDP-3-dehydro-4,6-dideoxy-alpha-D-glucose +
CA   H(+) + L-methionine + NH4(+).
CC   -!- The enzyme, which is a member of the 'AdoMet radical' (radical SAM)
CC       family, is involved in biosynthesis of TDP-alpha-D-desosamine.
CC   -!- The reaction starts by the transfer of an electron from the reduced
CC       form of the enzyme's [4Fe-4S] cluster to S-adenosyl-L-methionine,
CC       spliting it into methionine and the radical 5-deoxyadenosin-5'-yl,
CC       which attacks the sugar substrate.
DR   Q9ZGH1, DESII_STRVZ;
//