ID   4.3.1.30
DE   dTDP-4-amino-4,6-dideoxy-D-glucose ammonia-lyase.
CA   dTDP-4-amino-4,6-dideoxy-alpha-D-glucose + AH2 + S-adenosyl-L-methionine
CA   = dTDP-3-dehydro-4,6-dideoxy-alpha-D-glucose + 5'-deoxyadenosine +
CA   L-methionine + A + NH4(+) + H(+).
CC   -!- The enzyme, which is a member of the 'AdoMet radical' (radical SAM)
CC       family, is involved in biosynthesis of TDP-alpha-D-desosamine.
CC   -!- The reaction starts by the transfer of an electron from the reduced
CC       form of the enzyme's [4Fe-4S] cluster to S-adenosyl-L-methionine,
CC       spliting it into methionine and the radical 5-deoxyadenosin-5'-yl,
CC       which attacks the sugar substrate.
DR   Q9ZGH1, DESII_STRVZ;
//