ID 4.4.1.31 DE phycoerythrocyanin alpha-cysteine-84 phycoviolobilin lyase/isomerase. AN phycoviolobilin phycoerythrocyanin-alpha84-cystein-lyase. CA phycoviolobilin-L-cysteinyl(84)-[phycoerythrocyanin alpha-subunit] = CA (2R,3E)-phycocyanobilin + apo-L-cysteinyl(84)-[phycoerythrocyanin alpha- CA subunit]. CC -!- The enzyme, characterized from the cyanobacteria Nostoc sp. PCC 7120 CC and Mastigocladus laminosus, catalyzes the covalent attachment of the CC phycobilin chromophore phycocyanobilin to cysteine 84 of the beta CC subunit of the phycobiliprotein phycoerythrocyanin and its CC isomerization to phycoviolobilin. //