ID 4.4.1.33 DE R-phycocyanin alpha-cysteine-84 phycourobilin lyase/isomerase. CA phycourobilin-L-cysteinyl(84)-[R-phycocyanin alpha-subunit] = (2R,3E)- CA phycoerythrobilin + apo-L-cysteinyl(84)-[R-phycocyanin alpha-subunit]. CC -!- The enzyme, characterized from the cyanobacterium Synechococcus sp. CC WH8102, catalyzes the covalent attachment of the phycobilin CC chromophore phycoerythrobilin to cysteine 84 of the alpha subunit of CC the phycobiliprotein R-phycocyanin and its isomerization to CC phycourobilin. //