ID 4.4.1.39 DE C-phycoerythrin alpha-cysteine-82 phycoerythrobilin lyase. CA phycoerythrobilin-L-cysteinyl(82)-[C-phycoerythrin alpha-subunit] = CA (2R,3E)-phycoerythrobilin + apo-L-cysteinyl(82)-[C-phycoerythrin alpha- CA subunit]. CC -!- The enzyme, characterized from the cyanobacterium Microchaete CC diplosiphon, catalyzes the attachment of the phycobilin chromophore CC (3E)-phycoerythrobilin (PEB) to cysteine 82 of the alpha subunit of CC the phycobiliprotein C-phycoerythrin. CC -!- The numbering used here corresponds to the enzyme from Microchaete CC diplosiphon, and could vary slightly in other organisms. CC -!- Activity is greatly enhanced in the presence of the chaperone-like CC protein CpeZ. CC -!- The reaction could also be catalyzed by EC 4.4.1.29, but much less CC efficiently. //