ID 5.3.3.23 DE S-methyl-5-thioribulose 1-phosphate isomerase. AN 5-methylthioribulose-1-phosphate isomerase. CA (1) S-methyl-5-thio-D-ribulose 1-phosphate = S-methyl-1-thio-D-xylulose CA 5-phosphate. CA (2) S-methyl-5-thio-D-ribulose 1-phosphate = S-methyl-1-thiol-D-ribulose CA 5-phosphate. CC -!- The enzyme, characterized from the bacterium Rhodospirillum rubrum, CC participates in methionine salvage from S-methyl-5'-thioadenosine. CC -!- It is a RuBisCO-like protein (RLP) that is not capable of carbon CC fixation, and catalyzes an isomerization reaction that converts CC S-methyl-5-thio-D-ribulose 1-phosphate to a 3:1 mixture of S-methyl- CC 1-thioxylulose 5-phosphate and S-methyl-1-thioribulose 5-phosphate. CC -!- The reaction is an overall 1,3-proton transfer, which likely consists CC of two 1,2-proton transfer events. DR Q2RSU7, RLP_RHORT ; //