ID 5.3.99.12 DE lachrymatory-factor synthase. AN LFS. CA (E)-alk-1-en-1-SO-peroxol = (Z)-alkanethial oxide. CC -!- The enzyme is responsible for production of the irritating CC lachrymatory factor that is released by onions and related species CC when they are chopped. CC -!- It acts on the product of EC 4.4.1.4. CC -!- The enzyme from Allium cepa (onion) acts on (E)-prop-1-en-1- CC SO-peroxol and produces (Z)-propanethial oxide, while the enzyme from CC Allium siculum (honey garlic) acts on (E)-but-1-en-1-SO-peroxol and CC produces (Z)-butanethial oxide. //