ID   5.4.4.6
DE   9,12-octadecadienoate 8-hydroperoxide 8S-isomerase.
AN   (8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate mutase ((7S,8S,9Z,12Z)-
AN   5,8-dihydroxy-9,12-octadecadienoate-forming).
CA   (8R,9Z,12Z)-8-hydroperoxyoctadeca-9,12-dienoate = (7S,8S,9Z,12Z)-7,8-
CA   dihydroxyoctadeca-9,12-dienoate.
CC   -!- The bifunctional enzyme from Gaeumannomyces graminis catalyzes the
CC       oxidation of linoleic acid to (8R,9Z,12Z)-8-hydroperoxyoctadeca-9,12-
CC       dienoate (cf. EC 1.13.11.60), which is then isomerized to
CC       (7S,8S,9Z,12Z)-5,8-dihydroxyoctadeca-9,12-dienoate.
CC   -!- Formerly EC 1.13.11.44.
DR   Q9UUS2, LIDS_GAEGR ;  G4N4J5, LIDS_PYRO7 ;
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