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ENZYME

ENZYME entry: EC 5.5.1.22

PURL: https://purl.expasy.org/enzyme/EC/5.5.1.22
Accepted Name
(-)-bornyl diphosphate synthase
Alternative Name(s)
(-)-bornyl pyrophosphate cyclase
bornyl pyrophosphate synthase
Reaction catalysed
(2E)-geranyl diphosphate = (2R,4S)-bornyl diphosphate
Comment(s)
  • The enzyme from Tanacetum vulgare (tansey) can also use (3S)-linalyl diphosphate or more slowly neryl diphosphate in vitro.
  • The reaction proceeds via isomeration of geranyl diphosphate to (3S)- linalyl diphosphate.
  • The oxygen and phosphorus originally linked to C-1 of geranyl diphosphate end up linked to C-2 of (-)-bornyl diphosphate. cf. EC 5.5.1.8.
Cross-references
BRENDA5.5.1.22
EC2PDB5.5.1.22
ExplorEnz5.5.1.22
KEGG Ligand Database for Enzyme Nomenclature5.5.1.22
IUBMB Enzyme Nomenclature5.5.1.22
MEDLINEFind literature relating to 5.5.1.22
MetaCyc5.5.1.22
Rhea expert-curated reactions5.5.1.22

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All ENZYME / UniProtKB/Swiss-Prot entries corresponding to 5.5.1.-
All ENZYME / UniProtKB/Swiss-Prot entries corresponding to 5.5.-.-
All ENZYME / UniProtKB/Swiss-Prot entries corresponding to 5.-.-.-