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ENZYME

ENZYME entry: EC 5.5.1.8

Accepted Name
(+)-bornyl diphosphate synthase
Alternative Name(s)
bornyl pyrophosphate synthase
bornyl pyrophosphate synthetase
geranyl-diphosphate cyclase
Reaction catalysed
(2E)-geranyl diphosphate = (2S,4R)-bornyl diphosphate
Comment(s)
  • The enzyme from Salvia officinalis (sage) can also use (3R)-linalyl diphosphate or more slowly neryl diphosphate in vitro.
  • The reaction proceeds via isomeration of geranyl diphosphate to (3R)- linalyl diphosphate.
  • The oxygen and phosphorus originally linked to C-1 of geranyl diphosphate end up linked to C-2 of (+)-bornyl diphosphate. cf. EC 5.5.1.22.
Cross-references
BRENDA5.5.1.8
EC2PDB5.5.1.8
ExplorEnz5.5.1.8
PRIAM enzyme-specific profiles5.5.1.8
KEGG Ligand Database for Enzyme Nomenclature5.5.1.8
IUBMB Enzyme Nomenclature5.5.1.8
IntEnz5.5.1.8
MEDLINEFind literature relating to 5.5.1.8
MetaCyc5.5.1.8
Rhea expert-curated reactions5.5.1.8
UniProtKB/Swiss-Prot
O81192, BPPS_SALOF

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