ENZYME entry: EC 2.3.1.111

Accepted Name
Mycocerosate synthase.
Reaction catalysed
Acyl-CoA + n methylmalonyl-CoA + 2n NADPH <=> multi-methyl-branched acyl-CoA + n CoA + n CO(2) + 2n NADP(+) + n H(2)O
Comment(s)
Elongates CoA esters of fatty acids from C(6) to C(20) by incorporation of methylmalonyl, but not malonyl, residues, to form multimethyl-branched fatty-acyl-CoA such as 2,4,6,8-tetramethyl- octosanoyl-CoA.
Cross-references
PROSITEPDOC00529
BRENDA2.3.1.111
EC2PDB2.3.1.111
ExplorEnz2.3.1.111
PRIAM enzyme-specific profiles2.3.1.111
KEGG Ligand Database for Enzyme Nomenclature2.3.1.111
IUBMB Enzyme Nomenclature2.3.1.111
IntEnz2.3.1.111
MEDLINEFind literature relating to 2.3.1.111
MetaCyc2.3.1.111
UniProtKB/Swiss-Prot
Q02251, MCAS_MYCBO

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