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ENZYME entry: EC 188.8.131.52
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|Trans,trans-farnesyl diphosphate aristolochene-lyase.|
|(2E,6E)-farnesyl diphosphate <=> aristolochene + diphosphate|
- The initial internal cyclization produces the monocyclic intermediate
germacrene A; further cyclization and methyl transfer converts the
intermediate into aristolochene.
- While in some species germacrene A remains as an enzyme-bound
intermediate, it has been shown to be a minor product of the reaction
in Penicillium roqueforti (see also EC 184.108.40.206).
- Aristolochene is the likely parent compound for a number of
sesquiterpenes produced by filamentous fungi.
- Formerly EC 220.127.116.11 and EC 18.104.22.168.
|PRIAM enzyme-specific profiles||22.214.171.124|
|KEGG Ligand Database for Enzyme Nomenclature||126.96.36.199|
|IUBMB Enzyme Nomenclature||188.8.131.52|
|MEDLINE||Find literature relating to 184.108.40.206|
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entries corresponding to 4.2.3.-
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