ENZYME entry: EC 1.3.1.122
Accepted Name |
(S)-8-oxocitronellyl enol synthase.
|
Alternative Name(s) |
Iridoid synthase. |
Reaction catalysed |
(S)-8-oxocitronellyl enol + NAD(P)(+) <=> (6E)-8-oxogeranial + NAD(P)H |
Comment(s) |
- Isolated from the plants Catharanthus roseus, Olea europaea (common
olive), and several Nepeta species.
- The enzyme reduces 8-oxogeranial, generating an unstable product that
is subsequently cyclized into several possible products, either non-
enzymically or by dedicated cyclases.
- The products, known as iridoids, are involved in the biosynthesis of
many indole alkaloids.
- Cf. EC 1.3.1.123.
- Formerly EC 1.3.1.99.
|
Cross-references |
BRENDA | 1.3.1.122 |
EC2PDB | 1.3.1.122 |
ExplorEnz | 1.3.1.122 |
PRIAM enzyme-specific profiles | 1.3.1.122 |
KEGG Ligand Database for Enzyme Nomenclature | 1.3.1.122 |
IUBMB Enzyme Nomenclature | 1.3.1.122 |
IntEnz | 1.3.1.122 |
MEDLINE | Find literature relating to 1.3.1.122 |
MetaCyc | 1.3.1.122 |
Rhea expert-curated reactions | 1.3.1.122 |
UniProtKB/Swiss-Prot |
|
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