ENZYME entry: EC 1.3.1.123
| Accepted Name |
|---|
| 7-epi-iridoid synthase.
|
| Reaction catalysed |
|---|
| (R)-8-oxocitronellyl enol + NADP(+) <=> (6E)-8-oxogeranial + NADPH |
| Comment(s) |
|---|
- The enzyme, characterized from the plant Antirrhinum majus
(snapdragon), is involved in biosynthesis of 7-epi-iridoids such as
antirrhinoside.
- The enzyme catalyzes the stereospecific reduction of 8-oxogeranial,
forming an unstable product that in the absence of additional cylases
undergoes spontaneous cyclization to (-)-cis,trans-nepetalactol.
- Cf. EC 1.3.1.122.
|
| Cross-references |
|---|
| BRENDA | 1.3.1.123 |
| EC2PDB | 1.3.1.123 |
| ExplorEnz | 1.3.1.123 |
| PRIAM enzyme-specific profiles | 1.3.1.123 |
| KEGG Ligand Database for Enzyme Nomenclature | 1.3.1.123 |
| IUBMB Enzyme Nomenclature | 1.3.1.123 |
| IntEnz | 1.3.1.123 |
| MEDLINE | Find literature relating to 1.3.1.123 |
| MetaCyc | 1.3.1.123 |
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