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ENZYME entry: EC 2.3.1.277

Accepted Name
2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate synthase.
Reaction catalysed
A medium-chain 3-oxoacyl-[acyl-carrier protein] + glycerone phosphate <=> 2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate + a holo-[acyl-carrier protein]
Comment(s)
The enzyme catalyzes the first committed step in the biosynthesis of gamma-butyrolactone autoregulators that control secondary metabolism and morphological development in Streptomyces bacteria.
Cross-references
BRENDA2.3.1.277
EC2PDB2.3.1.277
ExplorEnz2.3.1.277
PRIAM enzyme-specific profiles2.3.1.277
KEGG Ligand Database for Enzyme Nomenclature2.3.1.277
IUBMB Enzyme Nomenclature2.3.1.277
IntEnz2.3.1.277
MEDLINEFind literature relating to 2.3.1.277
MetaCyc2.3.1.277

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