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ENZYME entry: EC 4.2.3.114

Accepted Name
Gamma-terpinene synthase.
Reaction catalysed
Geranyl diphosphate <=> gamma-terpinene + diphosphate
Cofactor(s)
Mg(2+).
Comment(s)
  • Isolated from Thymus vulgaris (thyme), Citrus limon (lemon), Citrus unshiu (satsuma) and Origanum vulgare (oregano).
  • The reaction involves a 1,2-hydride shift.
  • The 5-pro-S hydrogen of geranyl diphosphate is lost.
  • Traces of several other monoterpenoids are formed in addition to gamma-terpinene.
Cross-references
BRENDA4.2.3.114
EC2PDB4.2.3.114
ExplorEnz4.2.3.114
PRIAM enzyme-specific profiles4.2.3.114
KEGG Ligand Database for Enzyme Nomenclature4.2.3.114
IUBMB Enzyme Nomenclature4.2.3.114
IntEnz4.2.3.114
MEDLINEFind literature relating to 4.2.3.114
MetaCyc4.2.3.114
Rhea expert-curated reactions4.2.3.114
UniProtKB/Swiss-Prot
A0A0M3Q1Q3, GTPS1_THYVU;  R4JND9, GTPS3_THYCA;  R4JGL8, GTPSB_THYCA;  
R4JQT5, GTPSC_THYCA;  Q8L5K4, GTPS_CITLI;  E2E2P0, GTPS_ORIVU;  
G8H5N0, TPS17_SOLHA;  G5CV52, TPS17_SOLLC;  A0A1D6LTV0, TPS26_MAIZE;  
W6HUT3, TPS7_HEDCO;  

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