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ENZYME entry: EC 4.2.3.26

Accepted Name
R-linalool synthase.
Alternative Name(s)
(-)-3R-linalool synthase.
(3R)-linalool synthase.
Reaction catalysed
Geranyl diphosphate + H(2)O <=> (3R)-linalool + diphosphate
Cofactor(s)
Mn(2+) or Mg(2+).
Comment(s)
  • Geranyl diphosphate cannot be replaced by isopentenyl diphosphate, dimethylallyl diphosphate, farnesyl diphosphate or geranylgeranyl diphosphate as substrate.
  • Unlike many other monoterpene synthases, only a single product, (3R)- linalool, is formed.
Cross-references
BRENDA4.2.3.26
EC2PDB4.2.3.26
ExplorEnz4.2.3.26
PRIAM enzyme-specific profiles4.2.3.26
KEGG Ligand Database for Enzyme Nomenclature4.2.3.26
IUBMB Enzyme Nomenclature4.2.3.26
IntEnz4.2.3.26
MEDLINEFind literature relating to 4.2.3.26
MetaCyc4.2.3.26
Rhea expert-curated reactions4.2.3.26
UniProtKB/Swiss-Prot
Q84ZW8, ACSS_MAIZE;  Q2XSC5, LALIN_LAVAN;  Q9SPN0, LLOS1_ARTAN;  
Q9SPN1, LLOS5_ARTAN;  Q8H2B4, LLOS_MENAQ;  Q5SBP3, LLOS_OCIBA;  
D5SL78, LNSA_STRCL;  Q1XBU5, TPS5_SOLLC;  

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